Volume 177
Main Index

Issue 1, Pages 1-312 (11 September 1979)

1,1-Bis(phenylseleno)- and 1,1-bis(methylseleno)-alkyllithiums as building blocks in organic synthesis Pages 1-4 D. Van Ende, A. Cravador, A. Krief

Asymmetric alkylation of chiral N,N-disubstituted amides Pages 5-15 Marc Larcheveque, Eliana Ignatova, Thérèse Cuvigny

Addition of lithiated anions from arylacetonitriles to α,β-unsaturated aldehydes: solvent effect on 1,2 versus 1,4 addition under kinetic and/or thermodynamic control Pages 17-26 Lya Wartski, Mahmoud El-Bouz, Jacqueline Seyden-Penne

The carbanions of S-alkanoate-O,O-dialkyl phosphates: new synthons for reaching α, β-ethylenic esters Pages 27-34 M. Baboulene, G. Sturtz

Reaction of dilithiooximes with epoxides: a novel route to 1,4-diketones and its application to dihydrojasmone synthesis Pages 35-38 M. Bellassoued, P. Dardoize, M. Gaudemar

Vinylallenes : X. Preparation et reactivite des vinylallenyl-lithium Pages 39-52 Rene Baudouy, Françoise Delbecq, Jacques Gore

The preparation of substituted allyllithium reagents from allyltin compounds by transmetalation Pages 53-65 Dietmar Seyferth, Robert E. Mammarella

On a sulfurated grignard reagent equivalent to that of 2-chloromethyl-1,3-butadiene. New syntheses of ipsenol (2-methyl-6-methylene-7-octen-4-OL) and of ()-β-farnesene (()-7,11-dimethyl-3-methylene-1,6,10-dodecatriene) Pages 67-74 Bernard Cazes, Eric Guittet, Sylvestre Julia, Odile Ruel

Detection du transfert monoelectronique dans les additions nucleophiles des reactifs organometalliques. Induction asymetrique observee avec des esters ethyleniques chiraux Pages 75-90 D. Cabaret, Z. Welvart

Kinetics and mechanism of dimethylcadmium auto-oxidation in decane Pages 91-99 Yu. A. Alexandrov, S. A. Lebedev, N. V. Kuznetsova, G. A. Razuvaev

Interaction of tetracyanoethylene with some organo-tin and -mercury compounds Pages 101-115 O. A. Reutov, V. I. Rozenberg, G. V. Gavrilova, V. A. Nikanorov

Hydrometallation : IV. Hydroalumination of alkynes by hai(NR2)2 compounds catalyzed by Cp2TiCl2 Pages 117-128 E. C. Ashby, S. R. Noding

Rate constants and solvent isotope effects in the cleavage of picolyl- and (quinolylmethyl)-trimethylsilanes by sodium methoxide in methanol Pages 129-136 Giancarlo Seconi, Colin Eaborn, Alfred Fischer

Synthese de derives mono- ou disilicies au niveau d'un carbone fonctionnel Pages 137-144 Alphonse Ekouya, Raymond Calas, Jacques Dunogues, Claude Biran, Norbert Duffaut, (avec la collaboration technique de Paulette Lapouyade)

A regio- and stereoselective synthesis of 1,2-disubstituted vinylsilanes Pages 145-152 Michio Obayashi, Kiitiro Utimoto, Hitosi Nozaki

Homogeneous Catalysis : VII. The catalysis of isoprene hydrosilylation using metal atoms Pages 153-161 A. J. Cornish, M. F. Lappert, J. J. Macquitty‡, R. K. Maskell

Medium-sized organometallic derivatives : IX. transannular nucleophilic substitution in organosilicon and organogermanium eleven-membered rings Pages 163-170 Pierre Mazerolles, Alfréda Faucher, Jean-Pierre Beteille

Reactions of germylenes with nitrosobenzene and phenyl-t-butyl oxaziridine and its isomeric nitrone Pages 171-180 Pierre Riviere, Jacques Satgé, Annie Castel, André Cazes

Insertion de so2 dans la liaison titane—carbone : I. Diastereotopie et diastereoisomerie engendrees par la presence d'un atome de soufre chiral dans les produits d'insertion Pages 181-189 A. Dormond, C. Moise, A. Dahchour, J. Tirouflet

Insertion de SO2 dans la liaison titane—carbone : III. Stereochimie de la reaction au niveau de l'atome de titane et synthese de complexes presentant trois atomes chiraux (C, Ti, S) Pages 191-198 A. Dormond, C. Moise, A. Dahchour, J. C. Leblanc, J. Tirouflet

Protonation of the metal—metal bond in Fe2(μ-A)(μ-A′)(CO)4L2 complexes (A = A′ SC6H5, P(C6H5)2, P(CH3)2; A = SC6H5, A′ z.dbnd; P(C6H5)2; L z.dbnd; P(C6H5)3-n(CH3)n). : III. Experimental study of the influence of the A and A′ bridges on the basicity of the metal—metal bond Pages 199-209 M. S. Arabi, R. Mathieu, R. Poilblanc

Additions D'α-chloronitriles sur les olefines par catalyse redox Pages 211-220 Marc Julia, Georgette Le Thuillier, Lucien Saussine

Addition en catalyse redox d'halogenures benzyliques sur les doubles liaisons Pages 221-229 Jean-Luc Fabre, Marc Julia, Bernard Mansour, Lucien Saussine

Alkylation of ethyl bromomalonate by alkylcobaloximes Pages 231-237 M. Veber, K. N. V. Duong, F. Gaudemer, A. Gaudemer

Chimie organometallique : XII. Homologation du methanol par des catalyseurs homogenes derives du rhodium Pages 239-244 H. Dumas, J. Levisalles, H. Rudler

Total synthesis of steroid analogues by organometallic procedures Pages 245-253 G. P. Chiusoli, G. Salerno, E. Bergamaschi, G. D. Andreetti, G. Bocelli and, P. Sgarabotto

An evaluation of the PIV=S reduction—complexation by nickelocene as a synthetic tool in organophosphorus chemistry; towards the synthesis of functional phosphines with an optically active phosphorus centre Pages 255-263 François Mathey, François Mercier

A cyclobutadiene—palladium complex with a non-planar cyclobutadiene ring obtained from the palladium catalyzed dimerization of an ynamine Pages 265-272 Jean D'Angelo, Jacqueline Ficini, Serge Martinon, Claude Riche, Alain Sevin

Catalysis of the arylation of the reformatsky reagent by palladium or nickel complexes. Synthesis of aryl acid esters Pages 273-281 J. F. Fauvarque, A. Jutand

Group IB organometallic chemistry : XXXII. Arylcopper compounds ArnCun as intermediates in organometallic synthesis. Single-step synthesis and dynamic NMR spectroscopy of diorganotin dihalides Ar2-nRnSnX2 (Ar = 2-Me2NCH2C6H4 or (S)-2-Me2NCHMeC6H4; n = 0 or 1) Pages 283-292 Gerard Van Koten, Johann T. B. H. Jastrzebski, Jan G. Noltes

Organocuivreux vinyliques : IX. Addition de derives organiques du cuivre sur l'acetylene Pages 293-298 A. Alexakis, G. Cahiez, J. F. Normant

Some unusual aspect aspects of organocopper chemistry: lithium organocuprate reaction with some neopentylic p-tosylate esters Pages 299-307 Gary H. Posner, Kevin A. Babiak

Synthesis of phellanphos, an efficient chiral 1,2-diphosphine for asymmetric catalysis Pages 309-312 M. Lauer, O. Samuel, H. B. Kagan

Issue 2, Pages 313-454 (18 September 1979)

Insertion of acetylenes in the Pd---Pd bond of Pd2 (Ph2 PCH2 PPh2)2 Cl2 Pages C22-C26 Alan L. Balch, Chung-Li Lee, Catherine H. Lindsay, Marilyn M. Olmstead

Nickel-catalyzed allylation of norbornene Pages C29-C31 M. Catellani, G. P. Chiusoli, E. Dradi, G. Salerno

Coordination, Oligomerisation and Transfer Hydrogenation of Acetylenes by Some Ruthenium and Osmium Carboxylato Complexes: Crystal and Molecular Structure of (1,4-Diphenylbut-1-en-3-yn-2-yl)trifluoroacetato(carbonyl) bis(triphenylphosphine)ruthenium(II) Pages C8-C12 Alan Dobson, David S. Moore, Stephen D. Robinson, Michael B. Hursthouse and, Lucy New

Nickel catalyzed asymmetric cross-coupling reaction between C6H5X and s-BuMgX. The influence of the nature of the halogens of the two reagents Pages C13-C15 Giambattista Consiglio, Oreste Piccolo, Franco Morandini

Siliciumorganische verbindungen : LXXI. Sila-paracyclophane Pages C16-C18 Leonhard Birkofer, Oskar Stuhl

Acces a des complexes du Cr et Mn a ligands isocyanures N-α carbonyles. proprietes et exemples d'utilisation de ces coordinats inhabituels. Pages C1-C7 P. Le Maux, G. Simonneaux, P. Caillet, G. Jaouen

Trichlorosilyl derivatives of the iron triad carbonyls Pages C27-C28 Roland K. Pomeroy

Bildung von tetramesitylmolybdän(V); ein homoleptisches σ-arylübergangsmetallkation Pages C19-C21 W. Seidel, I. Bürger

Errata Page C32

Metalation of alkyl aryl sulfones: qualitative and quantitative product determination Pages 313-321 A. Roggero, T. Salvatori, A. Proni, A. Mazzei

Kinetische untersuchung der reversiblen dimerisierung von o-phenylendioxidimethylsilan Pages 323-328 Heinrich Meyer, Jochen Klein, Armin Weiss

The dynamic behaviour of 1,8-Di-t-butylnaphthalene and its group IVA [(CH3)3M] analogues: an empirical force field study Pages 329-332 M. G. Hutchings, I. Watt

Base-catalysed hydrogen-exchange between organogermanium hydrides and methanol Pages 333-348 Colin Eaborn, Balbir Singh

Cyclopentadienylverbindungen des vierbindigen arsens und antimons Pages 349-356 Peter Jutzi, Manfred Kuhn

Ringöffnende acetylierung eines an kobalt koordinierten ringliganden vom divinylboran-typ Pages 357-363 G. E. Herberich, M. Thönnessen

Binuclear complexes of 1,4-diaza-3-methylbutadien-2-Yl-palladium(II) derivatives with palladium(II) and platinum(II) chlorides Pages 365-383 Bruno Crociani, Marino Nicolini, Antonio Mantovani

Reactions of 1,4-diaza-3-methylbutadien-2-ylpalladium(II) derivatives with chloro-bridged rhodium(I) complexes Pages 385-401 Bruno Crociani, Umberto Belluco, Pierluigi Sandrini

Reactions and properties of some trimethyleneplatinum(IV) complexes : VII. Kinetics and mechanism of displacement of cyclopropane by alkenes Pages 403-409 Richard J. Puddephatt, Peter J. Thompson, Charles F. H. Tipper

The crystal and molecular structures of trans-di-μ-thioethyldinitrosylbis (pentahaptocyclopentadienyl) dimolybdenum, [(η5-C5H5) Mo(NO) (SC2H5)]2, and cis-di-μ-thioisopropyldinitrosylbis (pentahaptocyclopentadienyl) dimolybdenum, [(η5-C5H5)-Mo(NO) (SCH(CH3)2] Pages 411-434 George R. Clark, David Hall, Karen Marsden

The kinetics of the reaction between manganese pentacarbonyl bromide and β-alanine Pages 435-442 John Burgess, Andrew J. Duffield

The Pyrolysis of Isonitrile Substituted Derivatives of Triosmium Dodecacarbonyl Pages 443-454 Martin J. Mays, Paul D. Gavens